Calibration method affects the measured δ2H and δ18O in soil water by direct H2Oliquid–H2Ovapour equilibration with laser spectroscopy     

Hongxiu Wang  Bingcheng Si  Dyan Pratt  Han Li  Xiaojun Ma 《水文研究》2020,34(2):506-516

The direct H₂O_liquid–H₂O_vapour equilibration method utilizing laser spectroscopy (DVE-LS) is a way to measure soil pore water stable isotopes. Various equilibration times and calibration methods have been used in DVE-LS. Yet little is known about their effects on the accuracy of the obtained isotope values. The objective of this study was to evaluate how equilibration time and calibration methods affect the accuracy of DVE-LS. We did both spiking and field soil experiments. For the spiking experiment, we applied DVE-LS to four soils of different textures, each of which was subjected to five water contents and six equilibration times. For the field soil experiment, we applied three calibration methods for DVE-LS to two field soil profiles, and the results were compared with cryogenic vacuum distillation (CVD)-LS. Results showed that DVE-LS demonstrated higher δ²H and δ¹⁸O as equilibration time increased, but 12 to 24 hr could be used as optimal equilibration time. For field soil samples, DVE-LS with liquid waters as standards led to significantly higher δ²H and δ¹⁸O than CVD-LS, with root mean square error (RMSE) of 8.06‰ for δ²H and 0.98‰ for δ¹⁸O. Calibration with soil texture reduced RMSE to 3.53‰ and 0.72‰ for δ²H and δ¹⁸O, respectively. Further, calibration with both soil texture and water content decreased RMSE to 3.10‰ for δ²H and 0.73‰ for δ¹⁸O. Our findings conclude that the calibration method applied may affect the measured soil water isotope values from DVE-LS.  相似文献   

Quality and timing of crowd-based water level class observations     

Simon Etter  Barbara Strobl  Ilja van Meerveld  Jan Seibert 《水文研究》2020,34(22):4365-4378

Crowd-based hydrological observations can supplement existing monitoring networks and allow data collection in regions where otherwise no data would be available. In the citizen science project CrowdWater, repeated water level observations using a virtual staff gauge approach result in time series of water level classes (WL-classes). To investigate the quality of these observations, we compared the WL-class data with “real” (i.e., measured) water levels from the same stream at a nearby gauging station. We did this for nine locations where citizen scientists reported multiple observations using a smartphone app and at 12 locations where signposts were set up to ask citizens to record observations on a paper form that could be left in a letterbox. The results indicate that the quality of the data collected with the app was better than for the forms. A possible explanation is that for each app location, a single person submitted the vast majority of the observations, whereas at the locations of the forms almost every observation was made by a different person. On average, there were more contributions between May and September than during the other months. Observations were submitted for a range of flow conditions, with a higher fraction of high flow observations for the locations were data were collected with the app. Overall, the results are encouraging for citizen science approaches in hydrology and demonstrate that the smartphone application and the virtual staff gauge are a promising approach for crowd-based water level class observations.  相似文献   

Characterization of complex groundwater flows in the environment of singular buildings by combining hydrogeological and non-destructive geophysical (ground-penetrating radar) techniques: Punta Begoña Galleries (Getxo,Spain)     

Jesus A. Uriarte  Laura Damas Mollá  Maialen Sagarna  Arantza Aranburu  Francisco García  Iñaki Antigüedad  Tomás Morales 《水文研究》2020,34(4):1004-1015

Locating and quantifying groundwater flow in many built-up areas are a priority with regard to its complete restoration. In this work, a hydrogeological survey of the surroundings of the Punta Begoña Galleries (Getxo, Bizkaia), built on a coastal cliff, was completed by using ground penetrating radar (GPR) testing. Thus, the preliminary characterization of soils and rocks in accessible areas of the cliff was first improved by hydrogeological information gathered from a single survey borehole, including permeability measurements by low pressure injection tests (LPTs) and continuous water level monitoring. As a complementary method, the non-destructive GPR technique was performed during both dry and wet hydrological periods and in tandem with the injection tests, providing more complete spatial and temporal images of water flows. Specifically, GPR allows mapping of flow paths in soils and assessing the continuity of fractures in rock masses. Altogether, this complementary approach provides greater knowledge of complex underground flow dynamics in built environments, thus making it easier to make decisions for their management.  相似文献   

Multivariate adaptive regression splines for estimating riverine constituent concentrations     

Hong Huang  Xiaoliang Ji  Fang Xia  Shuhui Huang  Xu Shang  Han Chen  Minghua Zhang  Randy A. Dahlgren  Kun Mei 《水文研究》2020,34(5):1213-1227

Regression-based methods are commonly used for riverine constituent concentration/flux estimation, which is essential for guiding water quality protection practices and environmental decision making. This paper developed a multivariate adaptive regression splines model for estimating riverine constituent concentrations (MARS-EC). The process, interpretability and flexibility of the MARS-EC modelling approach, was demonstrated for total nitrogen in the Patuxent River, a major river input to Chesapeake Bay. Model accuracy and uncertainty of the MARS-EC approach was further analysed using nitrate plus nitrite datasets from eight tributary rivers to Chesapeake Bay. Results showed that the MARS-EC approach integrated the advantages of both parametric and nonparametric regression methods, and model accuracy was demonstrated to be superior to the traditionally used ESTIMATOR model. MARS-EC is flexible and allows consideration of auxiliary variables; the variables and interactions can be selected automatically. MARS-EC does not constrain concentration-predictor curves to be constant but rather is able to identify shifts in these curves from mathematical expressions and visual graphics. The MARS-EC approach provides an effective and complementary tool along with existing approaches for estimating riverine constituent concentrations.  相似文献   

Assessing basin storage: Comparison of hydrometric- and tracer-based indices of dynamic and total storage     

Ciara D. Cooke  James M. Buttle 《水文研究》2020,34(9):2012-2031

Storage is a fundamental but elusive component of drainage basin function, influencing synchronization between precipitation input and streamflow output and mediating basin sensitivity to climate and land use/land cover (LULC) change. We compare hydrometric and isotopic approaches to estimate indices of dynamic and total basin storage, respectively, and assess inter-basin differences in these indices across the Oak Ridges Moraine (ORM) region of southern Ontario, Canada. Dynamic storage indices for the 20 study basins included the ratio of baseflow to total streamflow (baseflow index BFI), Q ₉₉ flow and flow duration curve (FDC) slope. Ratios of the standard deviation of the streamflow stable isotope signal relative to that of precipitation were determined for each basin from a 1 year bi-weekly sampling program and used as indicators of total storage. Smaller ratios imply longer water travel times, smaller young water fractions (F _yw, < ~2–3 months in age) in streamflow and greater basin storage. Ratios were inversely related to BFI and Q ₉₉, and positively related to FDC slope, suggesting longer travel times and smaller F _yw for basins with stable baseflow-dominated streamflow regimes. Inter-basin differences in all indices reflected topographic, hydrogeologic and LULC controls on storage, which was greatest in steep, forest-covered headwaters underlain by permeable deposits with thick and relatively uniform unsaturated zones. Nevertheless, differential sensitivity of indices to controls on storage indicates the value of using several indices to capture more completely how basin characteristics influence storage. Regression relationships between storage indices and basin characteristics provided reasonable predictions of aspects of the streamflow regime of test basins in the ORM region. Such relationships and the underlying knowledge of controls on basin storage in this landscape provide the foundation for initial predictions of relative differences in streamflow response to regional changes in climate and LULC.  相似文献   

Snowpack disrupts relationship between young water fraction and isotope amplitude ratio; approximately one fifth of mountain streamflow less than one year old     

Éowyn M. S. Campbell  Igor Pavlovskii  M. Cathryn Ryan 《水文研究》2020,34(25):4762-4775

Previous “fraction of young water” (F_yw) estimates based on relative annual isotopic amplitudes in precipitation (A_p) and streamflow (A_s) produced low F_yw values in mountain catchments, which is contrary to extensive research that reports rapid water transmission in mountains. This study investigated this discrepancy by testing the effect of snow accumulation on the model that underpins the F_yw method. A Monte-Carlo analysis of simulations for 20,000 randomly-generated catchment model configurations used 10 years of precipitation inputs for the Upper Elbow River catchment in the Rocky Mountains (Alberta, Canada) to model discharge with and without snowpack storage of winter precipitation. Neither direct nor modified precipitation input produced a 1:1 relationship between A_s/A_p and F_yw, undermining the applicability of the original F_yw method in mountain watersheds with large seasonal snow accumulation. With snowpack-modified input a given A_s/A_p ratio corresponds to a range of F_yw values, which can still provide semi-quantitative information. In the small (435 km²) Elbow River catchment a F_yw range of 7–23% supports previous findings of rapid transmission in mountain catchments. Further analysis showed that the improved discharge prediction (Nash–Sutcliffe efficiency > 0.9) correlates with higher F_yw values and demonstrated that the interannual shifts in δ¹⁸O can be used to estimate of new water (<1 year) fraction in winter streamflow, and the estimate of 20% for the Elbow River further supports rapid transmission in mountain catchments.  相似文献   

What about reservoirs? Questioning anthropogenic and climatic interferences on water availability     

Abdullah Akbas  Jim Freer  Hasan Ozdemir  Paul D. Bates  M. Tufan Turp 《水文研究》2020,34(26):5441-5455

Water resources in semi-arid regions like the Mediterranean Basin are highly vulnerable because of the high variability of weather systems. Additionally, climate change is altering the timing and pattern of water availability in a region where growing populations are placing extra demands on water supplies. Importantly, how reservoirs and dams have an influence on the amount of water resources available is poorly quantified. Therefore, we examine the impact of reservoirs on water resources together with the impact of climate change in a semi-arid Mediterranean catchment. We simulated the Susurluk basin (23.779-km²) using the Soil and Water Assessment Tool (SWAT) model. We generate results for with (RSV) and without reservoirs (WRSV) scenarios. We run simulations for current and future conditions using dynamically downscaled outputs of the MPI-ESM-MR general circulation model under two greenhouse gas relative concentration pathways (RCPs) in order to reveal the coupled effect of reservoir and climate impacts. Water resources were then converted to their usages – blue water (water in aquifers and rivers), green water storage (water in the soil) and green water flow (water losses by evaporation and transpiration). The results demonstrate that all water resources except green water flow are projected to decrease under all RCPs compared to the reference period, both long-term and at seasonal scales. However, while water scarcity is expected in the future, reservoir storage is shown to be adequate to overcome this problem. Nevertheless, reservoirs reduce the availability of water, particularly in soil moisture stores, which increases the potential for drought by reducing streamflow. Furthermore, reservoirs cause water losses through evaporation from their open surfaces. We conclude that pressures to protect society from economic damage by building reservoirs have a strong impact on the fluxes of watersheds. This is additional to the effect of climate change on water resources.  相似文献   

刘家峡水库西南部水域表层沉积物重金属污染评价   总被引：1，自引：0，他引：1  

刘翔  郭建明  樊海龙  张生银  张顺存  雷天柱  王建丰 《沉积与特提斯地质》2020,40(4):1-10

为了研究刘家峡水库西南部水域表层沉积物中重金属的污染状况，对采集的55个表层沉积物样品中的6种重金属元素Cr、Cd、Ni、Cu、Zn和Pb的含量进行测试，其平均含量分别为77.03μg/g、0.16μg/g、33.53μg/g、32.09μg/g、291.77μg/g、22.44μg/g。在研究表层沉积物重金属含量空间分布的基础上，运用单因子污染指数法、内梅罗综合污染指数法、地累积指数法、潜在生态风险指数法，综合判断水库的受污染程度并对其潜在生态风险进行评估。6种元素的地累积指数排序依次为：Zn > Cu > Cd > Ni > Pb > Cr；潜在生态风险系数排序依次为：Cd > Cu > Pb > Zn > Ni > Cr；各区域重金属污染程度或潜在生态风险水平依次为黄河主河道 > 大夏河河口 > 黄河横剖面。综合4种方法的评价结果，认为对刘家峡水库西南部表层沉积物重金属污染及潜在生态风险评价贡献率较高的重金属污染因子是Zn、Cu和Cd；综合相关性分析与主成分分析，认为研究区沉积物重金属污染主要来源于两个方面：（1） Zn、Cu主要来源于生活污染或工业污染；（2） Cd主要来源于工农业活动产生的污染。  相似文献   

Bibliometric Analysis of Research Progress on Coastal Surface Water and Groundwater Interaction     

Tianzheng Cao  Dongmei Han  Xianfang Song  Wei Liu  Di Du 《地球科学进展》2020,35(2):154-166

The interactions among surface water, groundwater and seawater are closely related in the coastal area with complex hydrological conditions. A series of impacts from human activities and climate change are also more significant in this region. In order to understand the key knowledge and research status of surface water and groundwater interaction in coastal area, it is a useful method to analyze literatures in this research scope in the core database of Web of Science by using CiteSpace. The research achievements in this field were systematically sorted and potential research hotspots were explored, which may provide references for subsequent researches. The results show the following. \mathrm{①} The number of highly cited articles and highly burst articles in this research field has increased significantly since 2010. At present, this field is still in the development stage and has a broad research prospect. \mathrm{②} The United States, Australia, China and Germany have done plenty of researches on this issue and achieved a lot. At present, the number of research achievements supported by National Natural Science Foundation of China is in the lead over the world. \mathrm{③} Seawater intrusion, submarine groundwater discharge, the relationship between tide and hydrological conditions are the main research direction in this field. Hydrochemistry and isotopic analysis, and numerical simulation are the most important research methods in this field. \mathrm{④} The potential development directions and breakthroughs in this field include submarine groundwater discharge, the evolution of coastal mangrove wetlands, the migration and transformation of nutrients, the influences of different hydrological factors on coastal areas, and the impact of climate change on coastal areas. Overall, the future development of surface water and groundwater research in coastal areas is inseparable from the cross-integration of various disciplines, mutual verification of multiple methods and the introduction of new technical means.  相似文献   

基于SWAT模型的森林分布不连续流域水源涵养量多时间尺度分析   总被引：1，自引：0，他引：1  

林峰  陈兴伟  姚文艺  方艺辉  邓海军  吴杰峰  林炳青 《地理学报》2020,75(5):1065-1078

为解决森林分布不连续流域森林水源涵养功能及其多时间尺度特征的定量评价问题,根据分布式水文模型（SWAT）的特点,提出了反映森林斑块空间分布的水文响应单元划分方法,以及基于水量平衡法的森林不连续分布流域森林水源涵养量计算公式。以东南沿海的晋江流域为例,构建了2006年土地利用条件下的日时间步长SWAT模型,统计分析了2002—2010年降水条件下森林水源涵养量的时空变化规律。结果表明：① 构建的晋江流域SWAT模型精度较高,面积阈值为零生成的水文响应单元比较准确地反映流域森林斑块分布,提出的森林水源涵养量计算公式适用于森林空间分布不连续流域森林水源涵养量的多时间尺度分析,为流域森林水源涵养功能评价提供了一个新的方法。② 晋江流域森林水源年涵养量271.41~565.25 mm;月涵养量-29.15~154.59 mm;日尺度的极端降水期皆为正值,极端枯水期都为负值。表明年际之间不存在森林水源涵养的蓄丰补枯调节作用,但在年内的部分月份得到体现,而日尺度的森林蓄丰补枯功能充分发挥。从而揭示了不同时间尺度森林水源涵养量及其蓄丰补枯功能的差异。  相似文献